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The use of alternative fuels and among them the biofuels of 1st generation - fatty acid methyl esters FAME's and pure plants oils - for propulsion of IC engines is an important objective in several countries in order to save the fossil fuels and to limit the CO₂ production. The properties of bio-fuels and bio-blend-fuels can vary and this has an impact on the operation and emissions of diesel engines and on the modern exhaust aftertreatment systems. The present paper represents the most important results obtained with RME at AFHB, EMPA and EC-JRC. Most of the activities were performed in the network project BioExDi (Biofuels, Exhaust Systems Diesel) in collaboration between industry and research institutes.

The most efficient way and the best available technology (BAT) to radically reduce the critical diesel emission components particles (PM&NP) and nitric oxides (NOx) are combined exhaust gas aftertreatment systems (DPF+SCR). SCR (selective catalytic reduction) is regarded as the most efficient deNOx-system, diesel particle filters are most efficient for soot abatement. Today, several suppliers offer combined systems for retrofitting of HD vehicles. The presented results are part of the work in the international network project VERT *) dePN (de-activation, de-contamination, disposal of particles and NOx), which has the objectives to establish test procedures and quality standards and to introduce the SCR-, or combined DPF+SCR-systems in the VERT verification procedure.

The fatty acid methyl esters (FAME's) - in Europe mostly RME (Rapeseed methyl ester) - are used in several countries as alternative biogene diesel fuels in various blending ratios with fossil fuels (Bxx). Questions often arise about the influences of these biocomponents on the modern exhaust aftertreatment systems and especially on the regeneration of diesel particle filters (DPF). In the present work different regeneration procedures of DPF systems were investigated with biofuels B0, B20 & B100. The tested regeneration procedures were: - passive regenerations: DOC + CSF; CSF alone, and - active regenerations: standstill burner; fuel injections & DOC. During each regeneration on-line measurements of regulated and unregulated emission components (nanoparticles & FTIR) were conducted. It can be stated that the increased portion of RME in fuel provokes longer time periods to charge the filter with soot.

During the first decade of diesel particle filter development and deployment in cars, trucks, buses and underground sites, DPF regeneration methods were engineered that were compatible with the then prevalent high sulfur content in the fuel ≻ 2000 ppm. The mainly used methods were burners, electrical heaters, replaceable filters and non-precious metal fuel additives. Low sulfur diesel fuel became only available from 1996 in Sweden, 1998 in Switzerland, and after 2000 everywhere in Europe. Thus, the deployment of precious metal catalytic converters was feasible both as original equipment and retrofitting of in-use engines. The so-called CRT particle filters using PGM-catalysis for providing NO₂ for low temperature regeneration became very successful wherever ULSD was available.

1 Small off-road 4-stroke SI-engines have extraordinarily high pollutant emissions. These must be curtailed to comply with the new Swiss clean air act LRV 98. The Swiss environmental protection agency (BUWAL) investigated the state of the technology. The aim was a cleaner agricultural walk behind mower with a 10kW 4-stroke SI-engine. Two engine designs were compared: side-valve and OHV. A commercially available 3-way catalytic converter system substantially curtailed emissions: In the ISO 8178 G test-cycle-average, HC was minimized to 8% and CO to 5% of raw emissions. At part load points, the residual emission was < 1%. Simultaneously, fuel consumption improved 10%. Using a special gasoline (Swiss standard SN 181 163), the aromatic hydrocarbons were curtailed, e.g. Benzene < 1%, and fuel consumption further improved. Those results were confirmed in field tests. The engine is approved for retrofitting.